Lewis Dot Structure
Lewis Dot Structures(also known as Lewis dot diagrams, electron dot diagrams, and electron dot structures) are diagrams that show the bonding between atoms of a molecule, and the lone pairs of electrons that may exist in the molecule. A Lewis structure can be drawn for any covalently-bonded molecule, as well as coordination compounds. The Lewis structure was named after
Gilbert N. Lewis who introduced it in his 1916 article The Atom and the Molecule. They are similar to electron dot diagrams in that the valence electrons in lone pairs are represented as dots, but they also contain lines to represent shared pairs in a chemical bond (single, double, triple, etc.).
The chemical symbol for the atom is surrounded by a number of dots corresponding to the number of
valence electrons.
For example,
- Hydrogen (H) has 1 valence electron, on a picture for the Lewis Dot Structure it has 1 dot
- Nitrogen (N) has 5 valence electrons, on a picture for the Lewis Dot Structure it has 5 dots
- Neon (Ne) has a full shell (8) of valence electrons, on a picture for the Lewis Dot Structure it has 8 dots
The formation of many common compounds can be visualized with the use of Lewis symbols and Lewis diagrams. In a Lewis symbol, the inner closed shells of electrons can be considered as included in chemical symbol for the element, and the outer shell or valence electrons are represented by dots. The dots are placed in four groups of one or two electrons each, with 8 electrons representing a closed shell or noble gas configuration. Lewis diagrams are useful for visualizing both ionic and covalent bonds.
In the idealized ionic bond, one atom gives up an electron to the other, forming positive and negative ions.
The conditions for bonds are that the total charge is zero and that each atom must have a noble gas electron configuration.
In the idealized covalent bond, two atoms share a pair of electrons, closing the shell for each of them.
The atoms share a pair of electrons, and that pair is
referred to as a bonding pair. The pairs of electrons which do not participate in the bond have traditionally been called "lone pairs". A single bond can be represented by the two dots of the bonding pair, or by a single line which represents that pair. The single line representation for a bond is commonly used in drawing Lewis structures for molecules.
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